ALLYLTRIS(TRIMETHYLSILYL)SILANE AS RADICAL ALLYLATING AGENT FOR ORGANIC HALIDES

被引：14

作者：

KOSUGI, M

KURATA, H

KAWATA, K

MIGITA, T

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 08期

关键词：

D O I：

10.1246/cl.1991.1327

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of allyltris(trimethylsilyl)silane with organic halides under the free radical conditions resulted in allylation of the halides in modrate to good yields. The presence of three trimethylsilyl groups on the silicon could enhance the homolytic dissociation of a Si-C bond in the beta-silylalkyl radical.

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页码：1327 / 1328

页数：2

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