TRIS(TERT-BUTYLCYCLOPENTADIENYL)NEODYMIUM-MU-CHLORO-TRIS(TETRAHYDROFURAN)LITHIUM, [ND(ETA(5)-(T)BUCP)3(MU-CL)LI(THF)3]

被引：6

作者：

GUAN, JW

SHEN, Q

JIN, SC

LIN, YH

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S010827019301193X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title complex, tris[2(eta5)-tert-butylcyclopentadi-enyl]-mu-chloro-1:2kappa2Cl-tris(tetrahydrofuran-1kappaO)lithiumneodymium, [Nd(C9H13)3(mu-Cl)Li(C4H8O)3], consists of the neutral moiety ((t)BuCp)3Nd linked to the cation [Li(thf)3]+ by a mu-Cl bridge. The Nd atom is coordinated by three eta5-bonded tert-butylcyclopentadienyl ((t)BuCp) ligands and a Cl- ion to form a slightly deformed tetrahedron. Nd-Cl = 2.797 (2), Li-Cl = 2.345 (9) angstrom and Nd-Cl-Li = 141.4 (3)-degrees.

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页码：891 / 893

页数：3

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