SYNTHESIS AND X-RAY STRUCTURE OF THE 1ST NONPOLYMERIC CHLOROTETRAKIS(CARBOXYLATO)-DIRUTHENIUM(II,III) COMPOUND

被引：23

作者：

BARRAL, MC

JIMENEZAPARICIO, R

ROYER, EC

RUIZVALERO, C

SAUCEDO, MJ

URBANOS, FA

机构：

[1] UNIV COMPLUTENSE MADRID,DEPT QUIM INORGAN,E-28040 MADRID,SPAIN

[2] UNIV COMPLUTENSE MADRID,FAC CIENCIAS QUIM,RAYOS X LAB,E-28040 MADRID,SPAIN

[3] CSIC,INST CIENCIAS MAT,E-28006 MADRID,SPAIN

来源：

INORGANIC CHEMISTRY | 1994年 / 33卷 / 12期

关键词：

D O I：

10.1021/ic00090a037

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compound Ru2Cl(mu-O2CC4H4N)4(thf).thf.H2O was prepared by reaction of Ru2Cl(mu-O2CCH3)4 with pyrrole-2-carboxylic acid in methanol/water and recrystallization from thf/petroleum ether. The crystal structure shows two ruthenium atoms linked by four bridging pyrrole-2-carboxylate ligands; the axial ligands are a chlorine atom and a thf molecule. The nonpolymer nature of this compound contrasts with the polymeric nature of all chlorotetrakis-(carboxylato)diruthenium(II,III) complexes described.

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页码：2692 / 2694

页数：3

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