AEROBIC OXIDATIONS OF UNSATURATED SUBSTRATES UNDER MUKAIYAMAS CONDITIONS - THE ROLE OF THE METAL AND OF THE SACRIFICIAL ALDEHYDE

被引：40

作者：

MASTRORILLI, P

NOBILE, CF

SURANNA, GP

LOPEZ, L

机构：

[1] POLITECN BARI,IST CHIM,I-70126 BARI,ITALY

[2] CNR,CTR MISO,I-70126 BARI,ITALY

[3] UNIV BARI,DIPARTIMENTO CHIM,I-70126 BARI,ITALY

来源：

TETRAHEDRON | 1995年 / 51卷 / 29期

关键词：

D O I：

10.1016/0040-4020(95)00410-A

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aerobic epoxidation of unsaturated substrates has been achieved under Mukaiyama's conditions (atmospheric pressure of dioxygen, in the presence of an excess of sacrificial aldehyde) with or without metal catalyst. The influence of light in non-catalysed reactions and the possible role of the aldehyde and of the metal complex in catalysed reactions are discussed. Two mechanistic pathways are proposed for Co(II) and Fe(III) [Ni(II)] catalytic centres.

引用

页码：7943 / 7950

页数：8

共 39 条

[1] THE SYNTHESIS OF SPIRO[ADAMANTANE-[1,2]DIOXETANES] [J].