SYNTHESIS AND CRYSTAL-STRUCTURE OF ME2SNCL2.(2-MEOC6H4N=CHC5H4N-2)

被引：13

作者：

CHATTOPADHYAY, TK ^{[1
]}

KUMAR, AK ^{[1
]}

ROY, A ^{[1
]}

BATSANOV, AS ^{[1
]}

SHAMURATOV, EB ^{[1
]}

STRUCHKOV, YT ^{[1
]}

机构：

[1] ACAD SCI USSR,INST ORGANOELEMENT CPDS,MOSCOW V-71,USSR

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 419卷 / 03期

关键词：

D O I：

10.1016/0022-328X(91)80240-K

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between Me2SnCl2 and the ligand 2-MeOC6H4N = CHC5H4N-2 in ethanol affords the monomeric (1:1) complex Me2SnCl2.(2-MeOC6H4N = CHC5H4N-2). An X-ray diffraction study has shown that the tin atom has a distorted octahedral co-ordination with trans-methyl groups. The methoxy oxygen of the ligand remains uncoordinated. The Sn-N bond lengths are > 2.39 angstrom.

引用

页码：277 / 282

页数：6

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