THERMODYNAMIC DATA OF ELECTROCHEMICAL LITHIUM INTERCALATION IN LIXMN2O4

被引:32
作者
BACH, S [1 ]
PEREIRARAMOS, JP [1 ]
BAFFIER, N [1 ]
MESSINA, R [1 ]
机构
[1] ECOLE NATL SUPER CHIM,CHIM APPL ETAT SOLIDE LAB,CNRS,URA 302,F-75231 PARIS 05,FRANCE
关键词
D O I
10.1016/0013-4686(92)85071-R
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Thermodynamic properties of the Li intercalation reaction into the "sol-gel" compound LiXMn2O4 (0.3 less-than-or-equal-to x less-than-or-equal-to 2) are investigated by potentiometric and coulometric measurements. The evolution of all the molar functions, DELTA-G(Li)BAR, DELTA-H(Li)BAR and DELTA-S(Li)BAR are in good agreement with the structural data and are correlated to the electrochemical behaviour of LiXMn2O4.
引用
收藏
页码:1301 / 1305
页数:5
相关论文
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