METAL HYDROXYCARBENE-LIKE INTERMEDIATES IN THE HYDROCARBONYLATION OF ALKENES TO ALCOHOLS CATALYZED BY RHODIUM COMPLEXES

被引：20

作者：

MACDOUGALL, JK ^{[1
]}

SIMPSON, MC ^{[1
]}

COLEHAMILTON, DJ ^{[1
]}

机构：

[1] UNIV ST ANDREWS,DEPT CHEM,ST ANDREWS KY16 9ST,FIFE,SCOTLAND

来源：

POLYHEDRON | 1993年 / 12卷 / 23期

关键词：

D O I：

10.1016/S0277-5387(00)80071-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Labelling studies show that aldehydes are not intermediates in the formation of heptanol from 1-hexene, CO and H-2 catalysed by [RhH(PEt3)3] in ethanol, whilst studies of model intermediates suggest that ethanol hydrogen bonds to or even protonates an acyl oxygen atom to give a hydroxycarbene-like intermediate in the direct formation of heptanol.

引用

页码：2877 / 2881

页数：5

共 15 条

[1] EXPERIMENTAL AND THEORETICAL-STUDIES OF THE REACTIONS OF ELECTROPHILES WITH CATIONIC FORMYL COMPLEXES - FORMATION OF METHOXY-CARBENE AND HYDROXY-CARBENE COMPLEXES OF RUTHENIUM(II) AND OSMIUM(II) [J].

BARRATT, DS ;

GLIDEWELL, C ;

COLEHAMILTON, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (04) :1079-1081

[2] UPON THE MECHANISM OF THE HOMOGENEOUS HYDROGENATION OF CARBON-MONOXIDE [J].

BARRATT, DS ;

COLEHAMILTON, DJ .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 306 (02) :C41-C44

[3] MECHANISTIC ASPECTS OF THE ALTERNATING COPOLYMERIZATION OF CARBON-MONOXIDE WITH OLEFINS CATALYZED BY CATIONIC PALLADIUM COMPLEXES [J].

BATISTINI, A ;

CONSIGLIO, G .

ORGANOMETALLICS, 1992, 11 (05) :1766-1769

[4] STRUCTURAL CHARACTERIZATION IN SOLUTION OF INTERMEDIATES IN RHODIUM-CATALYZED HYDROFORMYLATION AND THEIR INTERCONVERSION PATHWAYS [J].

BROWN, JM ;

KENT, AG .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (11) :1597-1607

[5] STRUCTURE AND DYNAMICS OF THE STABLE RHODIUM-ACYL COMPLEX FORMED DURING HYDROFORMYLATION [J].

BROWN, JM ;

KENT, AG .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (13) :723-725

[6] REACTION OF [WME(CO)3(ETA-C5H5)] WITH LIBHET3 - FORMATION AND REACTIONS OF THE ANIONIC FORMYL TRANS-[W(CHO)ME(CO)2(ETA-C5H5)] AND THE ANIONIC HYDRIDO ACYL TRANS-[WH(COME)(CO)2(ETA-C5H5)] [J].

GAUNTLETT, JT ;

MANN, BE ;

WINTER, MJ ;

WOODWARD, S .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (06) :1427-1432

[7] TRANSITION-METAL FORMYL COMPLEXES [J].

GLADYSZ, JA .

ADVANCES IN ORGANOMETALLIC CHEMISTRY, 1982, 20 :1-38

[8] CARBENE COMPLEXES OF IRON, MOLYBDENUM, AND RUTHENIUM - NEW ROUTE TO METAL-CARBENE DERIVATIVES [J].

GREEN, MLH ;

MITCHARD, LC ;

SWANWICK, MG .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (06) :794-+

[9]

Grubbs R. H., 1978, PROG INORG CHEM, V24, P1

[10] MIGRATORY-INSERTION REACTIONS OF OSMIUM(II) ETHYL COMPLEXES DERIVED FROM AN OSMIUM(0) ETHYLENE COMPLEX [J].

GRUNDY, KR ;

ROPER, WR .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 216 (02) :255-262

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