INVESTIGATION OF REACTION-KINETICS BY WAVEFRONT ANALYSIS

被引:16
作者
FIOLITAKIS, E
HOFFMANN, U
HOFMANN, H
机构
[1] Institut für Technische Chemie I, Universität Erlangen, 8520 Erlangen
关键词
D O I
10.1016/0009-2509(79)85113-1
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A new technique for kinetic investigations in fixed bed reactors, wave front analysis, is introduced in this paper. Use is made of Riemann's integration method to solve the linearized hyperbolic equations representing the dynamics of a homogeneous reaction in a packed tubular reactor. It is shown how the analysis of the front of the faster disturbance, in this system the concentration step, can be used for kinetic investigations. Wave front analysis is generalized for non-linear systems through Picard's iteration technique. © 1979.
引用
收藏
页码:677 / 683
页数:7
相关论文
共 12 条
[1]  
COURANT R, 1968, METHODEN MATH PHYSIK, V1
[2]  
Courant R., 1948, SUPERSONIC FLOW SHOC
[3]  
COURANT R, METHODEN MATH PHYSIK, V2
[4]  
FIOLITAKIS E, 1976, THESIS ERLANGEN
[5]  
Jeffrey A., 1964, NONLINEAR WAVE PROPA
[6]   TEMPERATURE PROFILES IN PACKED BEDS OF CATALYST DURING REGENERATION [J].
JOHNSON, BM ;
FROMENT, GF ;
WATSON, CC .
CHEMICAL ENGINEERING SCIENCE, 1962, 17 (11) :835-&
[7]   TRANSIENT-RESPONSE METHOD IN HETEROGENEOUS CATALYSIS [J].
KOBAYASHI, H ;
KOBAYASHI, M .
CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1974, 10 (02) :139-176
[8]  
KOBAYASHI M, 1977, 5TH CAN S CAT, P202
[9]  
SMIRNOW WI, 1961, LEHRGANG HOHEREN M 4
[10]  
Sommerfeld A, 1966, VORLESUNGEN THEORETI, VVI