DIVERGENTLY STEREOCONTROLLED REACTION OF AN ALLYLIC SILANE BEARING AN ASYMMETRIC ETHEREAL CARBON TOWARD ALDEHYDES

被引：32

作者：

NISHIGAICHI, Y

TAKUWA, A

JODAI, A

机构：

[1] Department of Chemistry, Faculty of Science, Shimane University, Matsue, 690, Nishikawatsu-cho

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 21期

关键词：

D O I：

10.1016/S0040-4039(00)79929-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Lewis acid mediated allylation of aldehydes by an allylsilane bearing an asymmetric ethereal functionality proceeded in divergently stereocontrolled manners, i.e., TiCl4 afforded the syn isomer, whereas BF3.OEt2 afforded the anti isomer predominantly.

引用

页码：2383 / 2386

页数：4

共 23 条

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