16-ELECTRON HALF-SANDWICH RU(II) THIOLATE COMPLEXES, RU(SAR)2(ETA-6-PARA-CYMENE) (AR = 2,6-DIMETHYLPHENYL AND 2,4,6-TRIISOPROPYLPHENYL)

被引:20
作者
MASHIMA, K [1 ]
MIKAMI, A [1 ]
NAKAMURA, A [1 ]
机构
[1] OSAKA UNIV, FAC SCI, DEPT MACROMOLEC SCI, TOYONAKA, OSAKA 560, JAPAN
关键词
D O I
10.1246/cl.1992.1473
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Treatment of [RuCl2(p-cymene)]2 with sodium 2,6-dimethylbenzenethiolate or sodium 2,4,6-triisopropylbenzenethiolate in methanol afforded a mononuclear five-coordinated ruthenium thiolate complex, Ru(SAr)2(p-cymene) (2a: Ar = 2,6-dimethylphenyl; 2b: 2,4,6-triisopropylphenyl), whose structure is determined by X-ray analysis of 2a.
引用
收藏
页码:1473 / 1476
页数:4
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