16-ELECTRON HALF-SANDWICH RU(II) THIOLATE COMPLEXES, RU(SAR)2(ETA-6-PARA-CYMENE) (AR = 2,6-DIMETHYLPHENYL AND 2,4,6-TRIISOPROPYLPHENYL)

被引：20

作者：

MASHIMA, K ^{[1
]}

MIKAMI, A ^{[1
]}

NAKAMURA, A ^{[1
]}

机构：

[1] OSAKA UNIV, FAC SCI, DEPT MACROMOLEC SCI, TOYONAKA, OSAKA 560, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 08期

关键词：

D O I：

10.1246/cl.1992.1473

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of [RuCl2(p-cymene)]2 with sodium 2,6-dimethylbenzenethiolate or sodium 2,4,6-triisopropylbenzenethiolate in methanol afforded a mononuclear five-coordinated ruthenium thiolate complex, Ru(SAr)2(p-cymene) (2a: Ar = 2,6-dimethylphenyl; 2b: 2,4,6-triisopropylphenyl), whose structure is determined by X-ray analysis of 2a.

引用

页码：1473 / 1476

页数：4

共 20 条

[1] SYNTHESIS OF CUBOIDAL (C5H4ME)4RU4E4 BY CONDENSATION OF (C5H4ME)RU(PPH3)2SH, (C5H4ME)RU(PPH3)2SEH
AMARASEKERA, J
RAUCHFUSS, TB
WILSON, SR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (01) : 14 - 16
[2] INTERCONVERSION OF PERSULFIDO, SULFUR HYDRIDE, AND HYDRIDE LIGANDS COORDINATED TO CPRU(PPH3)2+
AMARASEKERA, J
RAUCHFUSS, TB
[J]. INORGANIC CHEMISTRY, 1989, 28 (20) : 3875 - 3883
[3] PREPARATION AND REACTIONS OF DIRUTHENIUM THIOLATE COMPLEXES [CPSTARRU(MU-SR)3RUCPSTAR] (CPSTAR=ETA-5-C5ME5 R = I-PR, ET, CY, BZ, PH)
DEV, S
MIZOBE, Y
HIDAI, M
[J]. INORGANIC CHEMISTRY, 1990, 29 (23) : 4797 - 4801
[4] PREPARATION, PROPERTIES, AND SOME REACTIONS OF NOVEL RUTHENIUM THIOLATE COMPLEXES
DEV, S
IMAGAWA, K
MIZOBE, Y
CHENG, GB
WAKATSUKI, Y
YAMAZAKI, H
HIDAI, M
[J]. ORGANOMETALLICS, 1989, 8 (05) : 1232 - 1237
[5] RHODIUM AND IRIDIUM PERFLUOROPHENYLTHIOLATO COMPLEXES - THE X-RAY STRUCTURES OF [(C5ME5)IR(SC6F4H)2] AND [(C5ME5)2RH2(MU-SC6F5)3][(C5ME5)RH(SC6F5)3] AND EVIDENCE FOR NOVEL EQUILIBRIA IN SOLUTION
GARCIA, JJ
TORRENS, H
ADAMS, H
BAILEY, NA
MAITLIS, PM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (02) : 74 - 77
[6] SYNTHESIS AND REACTIONS OF SOME TRIPLE ALKOXO-BRIDGED AND THIOATO-BRIDGED ARENERUTHENIUM(II) COMPLEXES - X-RAY STRUCTURE DETERMINATION OF [RU2(ETA-C6H6)2(OME)3][BPH4]
GOULD, RO
STEPHENSON, TA
TOCHER, DA
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 263 (03) : 375 - 384
[7] PREPARATION OF THIOLATE-BRIDGED DIRUTHENIUM COMPLEXES WITH RU-RU SINGLE BOND
HIDAI, M
IMAGAWA, K
CHENG, G
MIZOBE, Y
WAKATSUKI, Y
YAMAZAKI, H
[J]. CHEMISTRY LETTERS, 1986, (08) : 1299 - 1302
[8] UNSATURATED ORGANOMETALLIC INTERMEDIATES - ELECTRONIC-STRUCTURE AND STRUCTURAL DYNAMICS OF (ETA-5-C5H5)MN(CO)2
HOFMANN, P
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1977, 16 (08): : 536 - 537
[9] INTRAMOLECULAR DYNAMICS IN THE MIXED-VALENCE CLUSTER (CH3C5H4)4RU4S4(2+) - OBSERVATION OF MOBILE METAL-METAL BONDS
HOUSER, EJ
AMARASEKERA, J
RAUCHFUSS, TB
WILSON, SR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (19) : 7440 - 7442
[10] THIOMETALATE COMPLEXES CONTAINING ARENE, THIOPHENE, AND CYCLOBUTADIENE COLIGANDS - ARE THIOMETALATE CLUSTERS GOOD MODELS FOR DESULFURIZATION CATALYSTS
HOWARD, KE
LOCKEMEYER, JR
MASSA, MA
RAUCHFUSS, TB
WILSON, SR
YANG, XG
[J]. INORGANIC CHEMISTRY, 1990, 29 (22) : 4385 - 4390

← 1 2 →