DISSOCIATION OF TRANS-2-ARYLCYCLOPROPYLAMMONIUM IONS AND RATES OF 2,4-DINITROPHENYLATION OF TRANS-2-ARYLCYCLOPROPYLAMINES

被引：2

作者：

FISCHER, A

MILLER, IJ

机构：

[1] University of Canterbury, Christchurch

[2] University of Victoria, Victoria, BC

来源：

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC | 1969年 / 09期

关键词：

D O I：

10.1039/j29690001135

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Neither the ρ value for dissociation of trans-2-arylcyclopropylammonium ions (0.52) nor that for dinitrophenylation of the amines (-0.46) implies a conjugative interaction across the cyclopropane ring. The effective σ value for 4-F in the dinitrophenylation is not significantly different from σ°4-F but that from the dissociation reaction is much lower than σ°4-F.

引用

页码：1135 / &

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