THERMODYNAMIC ACTIVATION PARAMETERS FOR RHODIUM COMPLEX CATALYZED CARBONYLATION OF PRIMARY ALCOHOLS

被引：24

作者：

HJORTKJAER, J

JORGENSEN, JCA

机构：

[1] Instituttet for Kemiindustri, Technical University of Denmark

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1978年 / 4卷 / 03期

关键词：

D O I：

10.1016/0304-5102(78)85015-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The kinetic parameters for the rhodium complex catalyzed carbonylation of primary alcohols, exemplified by ethanol have been examined. The demonstrated accordance between the thermodynamic activation parameters for methanol and ethanol confirms the previous conclusion that the transition state is an adduct formed by oxidative addition of alkyl iodide to the catalytic complex. © 1978.

引用

页码：199 / 203

页数：5

共 9 条

[1] BRODZKI D, 1976, B SOC CHIM FR, V12, P61
[2] PATTERNS OF ORGANOMETALLIC REACTIONS RELATED TO HOMOGENEOUS CATALYSIS
COLLMAN, JP
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1968, 1 (05) : 136 - &
[3] FORSTER D, 1976, J AM CHEM SOC, V98, P846, DOI 10.1021/ja00419a041
[4] RHODIUM COMPLEX CATALYZED METHANOL CARBONYLATION
HJORTKJAER, J
JENSEN, VW
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1976, 15 (01): : 46 - 49
[5] RHODIUM COMPLEX CATALYZED METHANOL CARBONYLATION - EFFECTS OF MEDIUM AND VARIOUS ADDITIVES
HJORTKJAER, J
JENSEN, OR
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1977, 16 (04): : 281 - 285
[6] HJORTKJAER J, UNPUBLISHED
[7] PAULIK FE, 1973, Patent No. 3772380
[8] PAULIK FE, 1969, Patent No. 1941449
[9] ROTH JF, 1971, CHEM TECHNOL, P600

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