THE KINETICS OF ELECTROPOLYMERIZATION

被引：15

作者：

SCHULTZE, JW

THYSSEN, A

机构：

[1] Institut für Physikalische Chemie, Elektrochemie der Heinrich-Heine-Universität Düsseldorf, D-4000 Düsseldorf 1

来源：

SYNTHETIC METALS | 1991年 / 43卷 / 1-2期

关键词：

D O I：

10.1016/0379-6779(91)91184-C

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

During the potentiostatic polymerization of aniline, the periods of nucleation, growth of nuclei and stationary growth can be distinguished. The rate determining step is an oxidation reaction with a transfer coefficient-alpha = 0.2 to 0.5 and E(a) = 57 kJ/mol. Evidence for branching and termination reactions is obtained using derivatives of aniline. Decomposition reactions (overoxidation) are proved in absence of the monomer.

引用

页码：2825 / 2830

页数：6

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