SYNTHESIS AND CRYSTAL-STRUCTURE OF [CU2(PHEN)2(MU-3-TTFTCH)2CD2(HFACAC)2]BULLET-2CH3CN [TTFTCH = 1,3,5-TRIS(TRIFLUOROMETHYL)-1,3,5-TRIOXYCYCLOHEXANE TRIANION]

被引：9

作者：

CASTRO, R

DURAN, ML

GARCIAVAZQUEZ, JA

ROMERO, J

SOUSA, A

CASTINEIRAS, A

HILLER, W

STRAHLE, J

机构：

[1] UNIV SANTIAGO DE COMPOSTELA,DEPT QUIM INORGAN,SANTIAGO,SPAIN

[2] UNIV TUBINGEN,INST ANORGAN CHEM,W-7400 TUBINGEN 1,GERMANY

来源：

POLYHEDRON | 1992年 / 11卷 / 10期

关键词：

D O I：

10.1016/S0277-5387(00)86928-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of 1,10-phenanthroline-bis(pyrimidine-2-thionato)cadmium(II) with Cu(hFacac)2 (hFacac = hexafluoroacetylacetonate) in acetonitrile gave [Cu2(phen)2(mu-3-TTFTCH)2Cd2(hFacac)2].2CH3CN [TTFTCH = 1,3,5-tris(trifluoromethyl)-1,3,5-trioxycyclohexane trianion]. The molecule is a tetranuclear complex with two copper and two coplanar cadmium atoms all bound together by bridging oxygen atoms belonging to the mu-3-TTFTCH3-ligands. Each copper has distorted square-planar coordination geometry and each cadmium a distorted octahedral environment.

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页码：1195 / 1200

页数：6

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