CARBON-CARBON ACTIVATION BY RHODIUM IN SOLUTION - SP(2)-SP(3) IS PREFERRED OVER SP(3)-SP(3) BOND-CLEAVAGE

被引：56

作者：

LIOU, SY ^{[1
]}

GOZIN, M ^{[1
]}

MILSTEIN, D ^{[1
]}

机构：

[1] WEIZMANN INST SCI,DEPT ORGAN CHEM,IL-76100 REHOVOT,ISRAEL

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 19期

关键词：

D O I：

10.1039/c39950001965

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of the ethyl-aromatic phosphine 1 with PhRh(PPh(3))(3) results in C-H activation, yielding complex 2, which upon treatment with H-2 undergoes selective cleavage of the sp(2)-sp(3) hybridized C-C bond forming ethane and complex 3; Ar-C cleavage is also observed upon reaction of 1 with H-2 and [RhCl(C8H14)(2)](2).

引用

页码：1965 / 1966

页数：2

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