SYNTHESIS AND STRUCTURAL AND CONFORMATIONAL STUDY OF SOME AMINES DERIVED FROM THE NORGRANATANE SYSTEM

被引：17

作者：

FERNANDEZ, MJ ^{[1
]}

HUERTAS, R ^{[1
]}

GALVEZ, E ^{[1
]}

机构：

[1] UNIV ALCALA DE HENARES, DEPT QUIM ORGAN, ALCALA DE HENARES, SPAIN

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1991年 / 246卷 / 3-4期

关键词：

D O I：

10.1016/0022-2860(91)80139-U

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A series of N-substituted-9-phenethyl-3-amino norgranatane derivatives have been synthesized and studied by H-1 and C-13 NMR spectroscopy. The compounds studied display in deuterochloroform the same preferred flattened chair-boat conformation with the disubstituted ring in a slightly distorted boat form. The arylamino groups, in the C-3-alpha position lie in the symmetry plane with respect to the bicyclic system.

引用

页码：359 / 366

页数：8

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