A KINETIC INVESTIGATION OF BUTYL ACRYLATE POLYMERIZATION

被引：40

作者：

DUBE, MA ^{[1
]}

RILLING, K ^{[1
]}

PENLIDIS, A ^{[1
]}

机构：

[1] UNIV WATERLOO,DEPT CHEM ENGN,WATERLOO N2L 3G1,ONTARIO,CANADA

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1991年 / 43卷 / 11期

关键词：

D O I：

10.1002/app.1991.070431121

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

An experimental investigation of the kinetics of the bulk free radical polymerization of butyl acrylate initiated with 2,2'-azobisisobutyronitrile (AIBN) was conducted at 50-degrees and 60-degrees-C using two initiator concentrations. Conversion levels were measured by gravimetry and were independently confirmed using replicate runs. The experiments, conducted in glass ampoules, were performed over the full conversion range. A mathematical model for process simulation purposes was developed. The model was able to predict conversion at the two temperatures and initiator concentrations, thus providing a better understanding of the butyl acrylate homopolymerization kinetics.

引用

页码：2137 / 2145

页数：9

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