MICROEMULSIONS AS MEDIA FOR ORGANIC-SYNTHESIS - SELECTIVE NITRATION OF PHENOL TO ORTHO-NITROPHENOL USING DILUTE NITRIC-ACID

被引:50
作者
CHHATRE, AS [1 ]
JOSHI, RA [1 ]
KULKARNI, BD [1 ]
机构
[1] NATL CHEM LAB,POONA 411008,MAHARASHTRA,INDIA
关键词
D O I
10.1006/jcis.1993.1245
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The paper reports near-selective nitration of phenol to ortho -nitrophenol using a suitably prepared microemulsion solution in the presence of dilute nitric acid. The case example indicates that microemulsions, besides enhancing the reaction rates, can also be selective to give the desired product. Microemulsion solution also affords the use of dilute acid as a nitrating agent. © 1993 Academic Press. All rights reserved.
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页码:183 / 187
页数:5
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