DIMENSIONAL REDUCTION OF RE6SE8CL2 - SHEETS, CHAINS, AND DISCRETE CLUSTERS COMPOSED OF CHLORIDE-TERMINATED [RE(6)Q(8)](2+) (Q=S, SE) CORES

被引：112

作者：

LONG, JR ^{[1
]}

WILLIAMSON, AS ^{[1
]}

HOLM, RH ^{[1
]}

机构：

[1] HARVARD UNIV,DEPT CHEM,CAMBRIDGE,MA 02138

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 02期

关键词：

CLUSTERS; RHENIUM COMPOUNDS; SOLID-STATE CHEMISTRY;

D O I：

10.1002/anie.199502261

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A general high‐temperature approach to reducing the dimensionality of cluster frameworks is formulated and employed in deconstructing the two‐dimensional Re6Se8Cl2 structure. The resulting new phases with [Re6Q8]2+ (Q  S, Se) cores exhibit two‐dimensional [Re6Se8Cl3]− sheets, one‐dimensional [Re6Q8Cl4]2− chains, and [Re6Q8Cl6]4− clusters. The structures of these phases are presented along with that of Tl5Re6Se8Cl7 which contains the unprecedented molecular cluster [Re6Se8Cl6]4− 1. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：226 / 229

页数：4

共 16 条

[1] K2CD2S3 VS CDS - CAN THE PROPERTIES OF QUANTUM-SIZED CDQ SEMICONDUCTORS BE EMULATED BY BULK ALKALI-METAL TERNARY A/CD/Q PHASES (Q = CHALCOGEN) [J].