SYNTHESIS AND PROPERTIES OF GERMYLENE-BRIDGED DIIRON COMPLEXES USING T-BUTYLGERMANE AS A PRECURSOR OF LIGANDS

被引：17

作者：

KAWANO, Y ^{[1
]}

SUGAWARA, K ^{[1
]}

TOBITA, H ^{[1
]}

OGINO, H ^{[1
]}

机构：

[1] TOHOKU UNIV, FAC SCI, DEPT CHEM, AOBA KU, SENDAI 980, JAPAN

来源：

CHEMISTRY LETTERS | 1994年 / 02期

关键词：

D O I：

10.1246/cl.1994.293

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photolysis of CpFe(CO)(2)SiMe(3) (Cp = eta-C5H5) in the presence of a new alkylgermane (t)BuGeH(3) afforded a mono(mu-germylene)diiron complex Cp(2)Fe(2)(CO)3(mu- GeH(t)Bu) (4) and a bis(mu-germylene)diiron complex Cp(2)Fe(2)(CO)(2)(mu-GeH(t)Bu)(2) (5). The structure of 4 was determined by X-ray crystallography.

引用

页码：293 / 296

页数：4

共 12 条

[1] STRUCTURAL AND DYNAMICAL PROPERTIES OF MU-DIMETHYLGERMYL-MU-CARBONYL-DICYCLOPENTADIENYLDICARBONYLDIIRON [J].

ADAMS, RD ;

BRICE, MD ;

COTTON, FA .

INORGANIC CHEMISTRY, 1974, 13 (05) :1080-1085

[2] SOME ASPECTS OF SILICON-TRANSITION-METAL CHEMISTRY [J].

AYLETT, BJ .

ADVANCES IN INORGANIC CHEMISTRY, 1982, 25 :1-133

[3] REACTION OF OCTACARBONYLDICOBALT WITH ORGANOSILANES, ORGANO-GERMANES, AND ORGANOSTANNANES - FORMATION, PROPERTIES, AND VIBRATIONAL-SPECTRA OF TRIMETHYLGERMYLTETRACARBONYLCOBALT AND RELATED COMPLEXES [J].

BRADLEY, GF ;

STOBART, SR .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (03) :264-269

[4] PHOTOREACTIONS OF SILYLIRON(II) COMPLEXES CP-ASTERISK-FE(CO)2SIME3 (CP-ASTERISK=ETA-5-C5H5,ETA-5-C5ME5) IN THE PRESENCE OF TRIHYDROSILANES [J].

KAWANO, Y ;

TOBITA, H ;

OGINO, H .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 428 (1-2) :125-143

[5] [CP2FE2(CO)3(MU-SITERT BU . NMI)]I - THE 1ST SILANETRIYLDIIRON COMPLEX [J].

KAWANO, Y ;

TOBITA, H ;

OGINO, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (07) :843-844

[6]

NICHOLSON BK, 1981, REV SILICON GERMANIU, V5, P67

[7] STRUCTURAL CHEMISTRY OF BINUCLEAR METAL CENTERS - CRYSTAL AND MOLECULAR-STRUCTURES OF THE MU-VINYL AND MU-METHYLCARBENE COMPLEXES [FE2(CO)2(MU-CO)(MU-CHCH2)(ETA-C5H2)2][BF4] AND [FE2(CO)2(MU-CO)(MU-CHME)(ETA-C5H5)2] [J].

ORPEN, AG .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (07) :1427-1431

[8] PHOTOCHEMICAL-REACTIONS OF (ETA-5-PENTAMETHYLCYCLOPENTADIENYL)DICARBONYLIRON ALKYL AND (ETA-5-PENTAMETHYLCYCLOPENTADIENYL)DICARBONYLIRON SILYL COMPLEXES - REVERSIBLE ETHYLENE INSERTION INTO AN IRON-SILICON BOND AND IMPLICATIONS FOR THE MECHANISM OF TRANSITION-METAL-CATALYZED HYDROSILATION OF ALKENES [J].

RANDOLPH, CL ;

WRIGHTON, MS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (12) :3366-3374

[9]

Tilley T. D., 1991, SILICON HETEROATOM B

[10]

Tilley T. D., 1989, CHEM ORGANIC SILICON, DOI DOI 10.1002/0470025107.CH24

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