MAGNETIC EXCHANGE COUPLING IN A NEARLY LINEAR IRON(III)NICKEL(II)NICKEL(II)IRON(III) COMPLEX

被引：49

作者：

KREBS, C ^{[1
]}

WINTER, M ^{[1
]}

WEYHERMULLER, T ^{[1
]}

BILL, E ^{[1
]}

WIEGHARDT, K ^{[1
]}

CHAUDHURI, P ^{[1
]}

机构：

[1] MAX PLANCK INST STRAHLENCHEM,D-45413 MULHEIM,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 18期

关键词：

D O I：

10.1039/c39950001913

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of LFe(III)Cl(3) with Ni-2(Hdfmp)(2) (L = 1,4,7-trimethyl-1,4,7-triazacyclononane, H(3)dfmp = 2-hydroxy-5-methylbenzene-1,3-dicarbaldehyde dioxime) produces in the presence of triethylamine, acetate and tetrafluoroborate ions, the dark brown complex [L(2)Fe(2)(mu(2)-O(2)CMe)(2)(dfmp)(2)(MeOH)(2)Ni-2](BF4)(2) which is characterized by X-ray crystallography and magnetic susceptibility measurements and found to have a paramagnetic ground state.

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页码：1913 / 1915

页数：3

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