A TRITERPENE FROM RUBUS-PINFAENSIS

被引：46

作者：

DURHAM, DG

LIU, XJ

RICHARDS, RME

机构：

[1] School of Pharmacy, The Robert Gordon University, Aberdeen

来源：

PHYTOCHEMISTRY | 1994年 / 36卷 / 06期

关键词：

RUBUS PINFAENSIS; ROSACEAE; ROOTS; PENTACYCLIC TRITERPENE; GLYCOSIDE; PINFAENSIC ACID;

D O I：

10.1016/S0031-9422(00)89744-7

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A new pentacyclic triterpene, pinfaensin, was isolated from the roots of Rubus pinfaensis and the structure elucidated by C-13 NMR methods. This triterpene, a glycoside of pinfaensic acid (glucosyl 23-formyl-2 alpha,3 beta,19 alpha-trihydroxyurs-12-en-28-oate), in order to achieve purification and characterization, was hydrolysed to previously unreported pinfaensic acid which on acetylation and methylation gave methyl diacetoxypinfaensate (methyl 2 alpha,3 beta-diacetoxy-23-formyl-19 alpha-hydroxyurs-12-en-oate).

引用

页码：1469 / 1472

页数：4

共 14 条

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