Silica-aerogel thermal expansion induced by submonolayer helium adsorption

被引:17
作者
Thibault, P
Prejean, JJ
Puech, L
机构
[1] Centre de Recherche Sur Les Très Basses Températures-CNRS, Associé à l'Université Joseph Fourier, 38042 Grenoble-Cédex 9
来源
PHYSICAL REVIEW B | 1995年 / 52卷 / 24期
关键词
D O I
10.1103/PhysRevB.52.17491
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We present measurements of the thermal expansion of silica-aerogels of various densities in the two following situations: thermal expansion of evacuated samples and the additional expansion due to He-4 adsorption on the silica surface in the temperature range 2-80 K. At the same time we measured the number of He-4 atoms adsorbed at the surface. To analyze the adsorption data we use a Brunauer-Emmett-Teller model, where we introduce a distribution of binding energies to take into account the surface heterogeneity. A simple model,involving the same distribution, allows us to relate the expansion to adsorption. We therefore determine some microscopic parameters for the adsorption energies and derive the elastic properties at different scales of the fractal structure.
引用
收藏
页码:17491 / 17500
页数:10
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