DECOMPOSITION OF VIBRATIONALLY EXCITED 1,1,2,2-TETRAFLUORO-1-CHLOROETHANE

被引：17

作者：

PRITCHARD, GO

PERONA, MJ

机构：

[1] Department of Chemistry, University of California, Santa Barbara

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 09期

关键词：

D O I：

10.1021/j100843a028

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The decomposition of the ground-electronic state vibrationally excited molecule CF2ClCF2H, formed in the photolysis of CF2ClCOCF2H in the 3130-Å region and at room temperature, is found to produce C2F4 by HCl elimination. The production of C2F3Cl by HF elimination is very minor. C2F4 is also produced in another unspecified reaction, and is removed from the system, presumably by radical and/or atom attack. The inherent experimental complications in this and related systems are discussed. The disproportionation/combination ratio for CF2Cl radicals is found to be 0.17.

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页码：2944 / +

页数：1

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