SYNTHESIS AND REACTIONS OF TRIORGANOTIN DIALKYLDITHIOPHOSPHATES

被引：86

作者：

SINGH, BP ^{[1
]}

SRIVASTAVA, G ^{[1
]}

MEHROTRA, RC ^{[1
]}

机构：

[1] UNIV RAJASTHAN,CHEM LABS,JAIPUR 302004,RAJASTHAN,INDIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 171卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)88061-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Triorganotin dialkyldithiophosphates, (RO)2P(=S)SSnR′3 (R = Et, i-Pr, n-Pr or Ph and R′ = Me, Et, Bu or Ph), have been synthesised by the interactions of triorganotin hydroxides, oxides and chlorides with dialkyldithiophosphoric acids, (RO)2P(=S)SH, or their (Na, NH4 or lead) salts in anhydrous benzene. An ester-type, structure is proposed, in which the diethyldithiophosphate moiety shows monodentate behaviour. © 1979.

引用

页码：35 / 41

页数：7

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