EXPERIMENTAL AND REDUCED DIMENSIONALITY QUANTUM RATE COEFFICIENTS FOR H-2(D2)+CN-]H(D)CN+H(D)

被引：99

作者：

SUN, Q ^{[1
]}

YANG, DL ^{[1
]}

WANG, NS ^{[1
]}

BOWMAN, JM ^{[1
]}

LIN, MC ^{[1
]}

机构：

[1] EMORY UNIV,DEPT CHEM,ATLANTA,GA 30322

来源：

JOURNAL OF CHEMICAL PHYSICS | 1990年 / 93卷 / 07期

关键词：

D O I：

10.1063/1.458663

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

New experimental rate coefficients are reported for the H 2(D2) + CN→H(D)CN + H(D) reactions over the temperature range 209 to 740 K for H2 and 250 to 740 K for D 2. Previous reduced dimensionality reaction probabilities for the reaction with H2, and new ones for the reaction with D2 are used to obtain analogous rate coefficients. In addition, reaction probabilities and rate coefficients for vibrationally excited reactants H 2 (v = 1), D2 (v = 1), or CN(v = 1) are presented. Comparisons of the calculated rate coefficients are made with the new and previous experiments, especially those of Sims and Smith [Chem. Phys. Lett. 149, 565 (1988)]. © 1990 American Institute of Physics.

引用

页码：4730 / 4739

页数：10

共 20 条

[1] KINETIC-STUDIES OF THE GAS-PHASE REACTIONS OF CN WITH O-2 AND H-2 FROM 294-K TO 1000-K [J].