KINETICS OF BULK-POLYMERIZATION OF ITACONIC ACID-DERIVATIVES .1. MONOPHENYL, MONOBENZYL AND MONO-2-PHENYLETHYL ITACONATES

被引：10

作者：

KATIME, I

MADOZ, A

VELADA, JL

机构：

[1] Grupo de Nuevos Materiales, Departamento de Quimica Física, Facultad de Ciencias, Universidad del País Vasco, Campus de Lejona, Apartado 644, Bilbao

来源：

THERMOCHIMICA ACTA | 1991年 / 189卷 / 01期

关键词：

D O I：

10.1016/0040-6031(91)87097-G

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The bulk polymerization of monophenyl, monobenzyl and mono-2-phenylethyl itaconates using alpha,alpha'-azobis(isobutyronitrile) (AIBN) as initiator at several temperatures has been studied by DTA. The order with respect to the monomer and the apparent activation energy of the polymerization process were determined. We found that the obtained values of the order with respect to the monomer are influenced by the diffusion process.

引用

页码：25 / 35

页数：11

共 12 条

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