FORMATION AND DECOMPOSITION OF PEROXOVANADIUM(V) COMPLEXES IN AQUEOUS-SOLUTION

被引：81

作者：

JASWAL, JS ^{[1
]}

TRACEY, AS ^{[1
]}

机构：

[1] SIMON FRASER UNIV,DEPT CHEM,BURNABY V5A 1S6,BC,CANADA

来源：

INORGANIC CHEMISTRY | 1991年 / 30卷 / 19期

关键词：

D O I：

10.1021/ic00019a030

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

V-51 NMR spectroscopy has been used to characterize the complexes formed between hydrogen peroxide and vanadate under near-neutral conditions in aqueous solution. The formation constants of the mono-, di-, and triperoxovanadates and tetraperoxodivanadate have been measured and the proton requirements for product formation determined. Under the conditions of these studies, the peroxide was found to undergo slow catalytic decomposition. Studies of the decomposition reaction suggested that the monoperoxovanadate is involved in a disproportionation of the hydrogen peroxide, which occurs by a combination of photo-and thermochemical mechanisms. The decomposition reaction is strongly inhibited by the presence of peptides.

引用

页码：3718 / 3722

页数：5

共 24 条

[1] ASYMMETRICALLY COORDINATED DIPEROXO COMPOUND - CRYSTAL-STRUCTURE OF K3[VO(O2)2(C2O4).H2O [J].