PHOTOINDUCED NOVEL SILYLATION OF CF-3-SUBSTITUTED BENZENES WITH DISILANE AND TRISILANE

被引：20

作者：

KAKO, M ^{[1
]}

MORITA, T ^{[1
]}

TORIHARA, T ^{[1
]}

NAKADAIRA, Y ^{[1
]}

机构：

[1] UNIV ELECTROCOMMUN,DEPT CHEM,CHOFU,TOKYO 182,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 08期

关键词：

D O I：

10.1039/c39930000678

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Irradiation of CF3-Substituted benzene in the presence of hexamethyldisilane and octamethyltrisilane causes two types of photosilylation, namely one at a benzylic position to give the corresponding benzylic silanes, and the other at aromatic ring to afford the corresponding phenylsilanes.

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收藏

页码：678 / 680

页数：3

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