STRUCTURE AND PROPERTIES OF MONO-MACROCYCLIC AND BIS-MACROCYCLIC PHOSPHORUS-COMPOUNDS

被引：10

作者：

DUTASTA, JP ^{[1
]}

VANOOSTENRICK, L ^{[1
]}

TINANT, B ^{[1
]}

DECLERCQ, JP ^{[1
]}

机构：

[1] UNIV CATHOLIQUE LOUVAIN,CHIM PHYS & CRISTALLOG LAB,B-1348 LOUVAIN,BELGIUM

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1993年 / 75卷 / 1-4期

关键词：

D O I：

10.1080/10426509308037365

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In order to complex cations and neutral molecules, hosts including the phosphoramide group have been designed and studied by nmr and X-ray crystallography. Macrocyclic derivatives containing the phosphoryl group can be easily synthesized from a diamine and an appropriate diaminophosphane. The complexation of alkaline and ammonium cations has been studied. The stability of the complexes is strongly related to the preorganized character of the phosphorus ligands. The formation of bis-macrocyclic compounds, bearing an asymmetric phosphorus atom is also reported.

引用

页码：63 / 66

页数：4

共 14 条

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