SYNTHESIS, CHARACTERIZATION, AND CATALYTIC PROPERTIES OF THE NEW TIZSM-12 ZEOLITE

被引:115
作者
TUEL, A
机构
[1] Institut de Recherches sur la Catalyse, CNRS, Villeurbanne
来源
ZEOLITES | 1995年 / 15卷 / 03期
关键词
D O I
10.1016/0144-2449(94)00059-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel titanium-containing zeolite TS-12 with the MTW-type structure has been synthesized under hydrothermal conditions in the presence of hexamethylene bis(diethylmethylammonium) cation (Et(2)MeN(+)C(3)H-6)(2) as templating agent. Physicochemical characterization of the samples showed that Ti atoms were part of the framework, probably in a tetrahedral coordination for low Ti contents. These zeolites have been shown to be active catalysts in the epoxidation of cyclohexene with various peroxides as oxidant.
引用
收藏
页码:236 / 242
页数:7
相关论文
共 32 条
  • [1] BELLUSSI G, 1990, 5TH P INT S SCI BAS
  • [2] THE STATE OF TI IN TITANOALUMINOSILICATES ISOMORPHOUS WITH ZEOLITE-BETA
    BLASCO, T
    CAMBLOR, MA
    CORMA, A
    PEREZPARIENTE, J
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (25) : 11806 - 11813
  • [3] INFRARED SPECTROSCOPIC INVESTIGATION OF TITANIUM IN ZEOLITES - A NEW ASSIGNMENT OF THE 960 CM(-1) BAND
    CAMBLOR, MA
    CORMA, A
    PEREZPARIENTE, J
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (06) : 557 - 559
  • [4] SYNTHESIS OF A TITANIUMSILICOALUMINATE ISOMORPHOUS TO ZEOLITE-BETA AND ITS APPLICATION AS A CATALYST FOR THE SELECTIVE OXIDATION OF LARGE ORGANIC-MOLECULES
    CAMBLOR, MA
    CORMA, A
    MARTINEZ, A
    PEREZPARIENTE, J
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (08) : 589 - 590
  • [5] ACTIVITY OF TI-BETA CATALYST FOR THE SELECTIVE OXIDATION OF ALKENES AND ALKANES
    CORMA, A
    CAMBLOR, MA
    ESTEVE, P
    MARTINEZ, A
    PEREZPARIENTE, J
    [J]. JOURNAL OF CATALYSIS, 1994, 145 (01) : 151 - 158
  • [6] CRYSTALLIZATION OF EU-1 AND EU-2 IN ALKALI AND ALKALI-FREE SYSTEMS
    DODWELL, GW
    DENKEWICZ, RP
    SAND, LB
    [J]. ZEOLITES, 1985, 5 (03): : 153 - 157
  • [7] FERRINI C, 1990, STUD SURF SCI CATAL, V55, P53
  • [8] CRYSTAL-STRUCTURE OF SILICA-ZSM-12 BY THE COMBINED USE OF HIGH-RESOLUTION SOLID-STATE MAS NMR-SPECTROSCOPY AND SYNCHROTRON X-RAY-POWDER DIFFRACTION
    FYFE, CA
    GIES, H
    KOKOTAILO, GT
    MARLER, B
    COX, DE
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (09) : 3718 - 3721
  • [9] DRS UV-VIS AND EPR SPECTROSCOPY OF HYDROPEROXO AND SUPEROXO COMPLEXES IN TITANIUM SILICALITE
    GEOBALDO, F
    BORDIGA, S
    ZECCHINA, A
    GIAMELLO, E
    LEOFANTI, G
    PETRINI, G
    [J]. CATALYSIS LETTERS, 1992, 16 (1-2) : 109 - 115
  • [10] GIORDANO G, 1989, ACS SYM SER, V398, P587