VIBRATIONAL STUDIES OF CYCLOPENTANE - EFFECT OF 10-FOLD BARRIER TO PSEUDOROTATION

被引：10

作者：

CHAO, TH

LAANE, J

机构：

[1] Department of Chemistry, Texas A and M University, College Station

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1978年 / 70卷 / 03期

关键词：

D O I：

10.1016/0022-2852(78)90173-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

A computer program has been used to determine the effects of 10-fold potential energy (V10) and kinetic energy (B10) terms on the pseudorotational energy levels of cyclopentane. The magnitudes of the calculated perturbations on the spectra have been evaluated, and the values of V10 and B10 are shown to be less than 20 and 0.2 cm-1, respectively. © 1978.

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页码：357 / 360

页数：4

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