INFLUENCE OF THE PHOSPHINE-LIGANDS IN THE H-1 AND P-31 NMR BEHAVIOR OF [(ETA-3-ALLYL)PT(PHOSPHINE)CL] COMPLEXES

被引:15
作者
CARTURAN, G [1 ]
SCRIVANTI, A [1 ]
LONGATO, B [1 ]
MORANDINI, F [1 ]
机构
[1] CNR,CTR STABILITA & REATTIVITA COMPOSTI COORDINAZIONE,I-35100 PADUA,ITALY
关键词
D O I
10.1016/S0022-328X(00)81859-8
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The 1H and 31P NMR spectra of (η3-allyl)Pt(PR3)Cl] (PR3 = PMe3, PCy3, P-t-Bu3, P-n-Bu3, PPh3, PPh2Me, PPhMe2 and P(p-Tol)3) complexes in chloroform have been studied. The results suggest that there is bonding interaction between the phosphine and the allyl group via central metal atom. © 1979.
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页码:91 / 97
页数:7
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