NOVEL ENTRY TO THE EREMOPHILANE AND VALENCANE SESQUITERPENES VIA A STEREOSELECTIVE INTRA-MOLECULAR DIELS-ALDER REACTION

被引：31

作者：

NAF, F

DECORZANT, R

THOMMEN, W

机构：

[1] Firmenich SA, Research Laboratories, Geneva

来源：

HELVETICA CHIMICA ACTA | 1979年 / 62卷 / 01期

关键词：

D O I：

10.1002/hlca.19790620117

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A general stereoselective entry to racemic eremophilane and valencane sesquiterpenes, via a common key intermediate and using an intramolecular Diels‐Alder reaction, is described. Copyright © 1979 Verlag GmbH & Co. KGaA, Weinheim

引用

页码：114 / 118

页数：5

共 20 条

[1] C-13 NMR-STUDIES .73. C-13 SPECTRA OF SEVERAL 10-METHYL-TRANS-DECALINS - FURTHER DEFINITION OF DESHIELDING ANTIPERIPLANAR-GAMMA EFFECT
AYER, WA
BROWNE, LM
FUNG, S
STOTHERS, JB
[J]. ORGANIC MAGNETIC RESONANCE, 1978, 11 (02): : 73 - 80
[2] C-13-NMR - SPECTROSCOPY OF NATURALLY OCCURRING SUBSTANCES .35. LABDANIC DITERPENES
BUCKWALTER, BL
BURFITT, IR
NAGEL, AA
WENKERT, E
NAF, F
[J]. HELVETICA CHIMICA ACTA, 1975, 58 (06) : 1567 - 1573
[3] STEREOSELECTIVE TOTAL SYNTHESIS OF (+/-)-EREMOLIGENOL, (+/-)-EREMOPHILENE, (+/-)-VALERIANOL, AND (+/-)-VALENCENE
COATES, RM
SHAW, JE
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1970, 35 (08) : 2597 - &
[4] CONIA JM, 1966, TETRAHEDRON LETT, P129
[5] C-13 MAGNETIC-RESONANCE .23. METHYLDECALINS/LI
DALLING, DK
GRANT, DM
PAUL, EG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (11) : 3718 - 3724
[6] C-13 NUCLEAR MAGNETIC-RESONANCE STUDIES .48. C-13 SPECTRA OF A VARIETY OF BICYCLIC KETONES
GROVER, SH
MARR, DH
STOTHERS, JB
TAN, CT
[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1975, 53 (09): : 1351 - 1361
[7] HARA S, 1975, TETRAHEDRON LETT, P1545
[8] Heathcock C.H., 1973, TOTAL SYNTHESIS NATU, V2, P197
[9] DEOXYGENATION OF ALPHA,BETA-UNSATURATED ALDEHYDES AND KETONES VIA CATECHOLBORANE REDUCTION OF CORRESPONDING TOSYLHYDRAZONES
KABALKA, GW
YANG, DTC
BAKER, JD
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1976, 41 (03) : 574 - 575
[10] TOTAL SYNTHESIS OF (+/-) ISONOOTKATONE - STEREOCHEMICAL STUDIES OF ROBINSON ANNELATION REACTION WITH 3-PENTEN-2-ONE
MARSHALL, JA
WARNE, TM
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1971, 36 (01) : 178 - &

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