CHEMISTRY IN CAGES - SYNTHESIS AND REVERSIBLE DECARBONYLATION OF [IR6(CO)16] ISOMERS IN NAY ZEOLITE

被引：33

作者：

KAWI, S ^{[1
]}

GATES, BC ^{[1
]}

机构：

[1] UNIV DELAWARE,CTR CATALYT SCI & TECHNOL,DEPT CHEM ENGN,NEWARK,DE 19716

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 15期

关键词：

D O I：

10.1039/c39910000994

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Ir(CO)2(acac)] in the cages of NaY zeolite is converted in CO at 1 bar (1 bar = 10(5) Pa) to the isomer of [Ir6(CO)16] with edge-bridging CO ligands and in CO + H-2 at 20 bar to the isomer of [Ir6(CO)16] with face-bridging ligands, either of which can be reversibly decarbonylated (Hacac = pentane-2-4-dione).

引用

页码：994 / 995

页数：2

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