C60H4 - KINETICS AND THERMODYNAMICS OF MULTIPLE ADDITION TO C-60

被引：104

作者：

HENDERSON, CC ^{[1
]}

ROHLFING, CM ^{[1
]}

ASSINK, RA ^{[1
]}

CAHILL, PA ^{[1
]}

机构：

[1] SANDIA NATL LABS,ALBUQUERQUE,NM 87185

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 07期

关键词：

D O I：

10.1002/anie.199407861

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The same compound, 1,2,3,4‐C60H4(1), is both the major kinetic product of the reaction of C60 or C60H2 with BH3 and the thermodynamically most stable isomer of C60H4. This was predicted by ab initio calculations and confirmed by experiment. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：786 / 788

页数：3

共 18 条

[1]

[Anonymous], 1993, ANGEW CHEM, V105, P1189

[2] HYDROGENATION OF BUCKMINSTERFULLERENE C-60 VIA HYDROZIRCONATION - A NEW WAY TO ORGANOFULLERENES [J].