SYNTHESES OF TETRANUCLEAR TUNGSTEN SULFIDE CLUSTERS WITH RAFT-TYPE AND TETRAHEDRAL CORE STRUCTURES

被引：16

作者：

KUWATA, S ^{[1
]}

MIZOBE, Y ^{[1
]}

HIDAI, M ^{[1
]}

机构：

[1] UNIV TOKYO,FAC ENGN,DEPT CHEM & BIOCHEM,BUNKYO KU,TOKYO 113,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 10期

关键词：

D O I：

10.1039/c39950001057

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of [W(N-2)(2)(PMe(2)Ph)(4)] With (Me(3)Si)(2)S-MeOH gives a raft-type tetratungsten sulfide cluster [W-4(mu(3)-S)(2)(mu-S)(4)(SH)(2)(PMe(2)Ph)(6)] 2, which is converted to a tetrahedral cluster [W-4(mu-S)(6)(PMe(2)Ph)(4)] 5 upon treatment with SnCl2 followed by reduction with Na/Hg; the molecular structures of 2 and 5 are determined by X-ray crystallography.

引用

页码：1057 / 1058

页数：2

共 27 条

[1] HEXAKIS(MU-3-THIO)PENTAKIS[(ETA-5-CYCLOPENTADIENYL)-TITANIUM], [(ETA-5-C5H5)TI)5(MU-3-S)6] - PREPARATION AND MOLECULAR AND ELECTRONIC-STRUCTURE [J].

BOTTOMLEY, F ;

EGHAREVBA, GO ;

WHITE, PS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (14) :4353-4354

[2] TRANSITION-METAL COMPLEXES WITH SULFUR-ATOMS AS LIGANDS .6. SYNTHESIS, PROPERTIES, AND STRUCTURE OF THE NICKEL CHALCOGENIDE COMPLEXES [NI-3(MU-3-S)2(PME3)6]2+, [NI-3(MU-3-S,SE)2(PET3)6]2+ AND [NI-9(MU-4-S)3(MU-3-S)6(PET3)6]2+ [J].

CECCONI, F ;

GHILARDI, CA ;

MIDOLLINI, S .

INORGANIC CHEMISTRY, 1983, 22 (25) :3802-3808

[3] METAL CHALCOGENIDE CLUSTER CHEMISTRY [J].

DANCE, I ;

FISHER, K .

PROGRESS IN INORGANIC CHEMISTRY, VOL 41, 1994, 41 :637-803

[4] THE STRUCTURAL CHEMISTRY OF METAL THIOLATE COMPLEXES [J].

DANCE, IG .

POLYHEDRON, 1986, 5 (05) :1037-1104

[5] SYNTHESES, PROPERTIES, AND MOLECULAR AND CRYSTAL-STRUCTURES OF (ME4N)4[S4ZN10(SPH)16] (ME4N)N[SE4CD10(SPH)16] - MOLECULAR SUPERTETRAHEDRAL FRAGMENTS OF THE CUBIC METAL CHALCOGENIDE LATTICE [J].

DANCE, IG ;

CHOY, A ;

SCUDDER, ML .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (21) :6285-6295

[6] CATALYTIC APPLICATIONS OF TRANSITION-METAL COMPLEXES WITH SULFIDE LIGANDS [J].

DUBOIS, MR .

CHEMICAL REVIEWS, 1989, 89 (01) :1-9

[7] TOWARDS NOVEL ORGANIC-SYNTHESIS ON MULTIMETALLIC CENTERS - SYNTHESES AND REACTIVITIES OF DINUCLEAR RUTHENIUM THIOLATE COMPLEXES [J].

HIDAI, M ;

MIZOBE, Y ;

MATSUZAKA, H .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 473 (1-2) :1-14

[8] 5-CO-ORDINATE COMPLEXES [MOH(SC(6)H(2)R(3)-2,4,6)(3)(PR'PH(2))] (R=ME OR PR(I), R'=ME OR ET) AND THEIR REACTIONS WITH NITROGEN DONORS - CRYSTAL-STRUCTURES OF [MOH(SC(6)H(2)PR(I)(3)-2,4,6)(3)(C(5)H(5)N)(PME(2)PH)] AND [PPH(4)][MOO(SC(6)H(2)PR(I)(3)-2,4,6)(4)] [J].

HUGHES, DL ;

LAZAROWYCH, NJ ;

MAGUIRE, MJ ;

MORRIS, RH ;

RICHARDS, RL .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (01) :5-15

[9] CATALYTIC N-N BOND-CLEAVAGE OF HYDRAZINES AT THE COORDINATIVELY UNSATURATED DIRUTHENIUM CENTER IN [CP-ASTERISK-RU(MU-SR)2RUCP-ASTERISK] (CP-ASTERISK = ETA-5-C5ME5 R = PR(I), 2,6-ME2C6H3) AND ISOLATION OF MU-PHENYLDIAZENE COMPLEXES [CP-ASTERISK-RU(MU-PHN=NH)(MU-SR)2RUCP-ASTERISK] [J].

KUWATA, S ;

MIZOBE, Y ;

HIDAI, M .

INORGANIC CHEMISTRY, 1994, 33 (17) :3619-3620

[10]

KUWATA S, 1993, J AM CHEM SOC, V115, P8449

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