APPLICATIONS OF CHROMIUM(II) CHLORIDE .4. CHROMIUM(II) REDUCTION OF SOME QUINONES
被引:10
作者:
HANSON, JR
论文数: 0引用数: 0
h-index: 0
机构:School of Molecular Sciences, University of Sussex
HANSON, JR
MEHTA, S
论文数: 0引用数: 0
h-index: 0
机构:School of Molecular Sciences, University of Sussex
MEHTA, S
机构:
[1] School of Molecular Sciences, University of Sussex
来源:
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC
|
1969年
/
18期
关键词:
D O I:
10.1039/j39690002349
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
Chromium(II) chloride is shown to be a useful reducing agent for benzoquinones and 1,4-naphthoquinones. 2-Alkyl-3-hydroxy-1,4-naphthoquinones are reduced to the trihydroxynaphthalenes by chromium(II) acetate and to the 1,3-dihydroxynaphthalenes by chromium(II) chloride in the presence of hypophosphorus acid.