FUNCTIONALIZATION OF A MULTIEPOXY RESIN BY METHACRYLIC COMPOUNDS AND STUDY OF ITS THERMAL-PROPERTIES

被引：2

作者：

BOUTEVIN, B

PARISI, JP

ROBIN, JJ

ROUME, C

机构：

[1] Laboratoire de Chimie Appliquée, URA CNRS D11930, Ecole Nationale Supérieure de Chimie de Montpellier, Montpellier Cedex 1, F-34053, 8, rue Ecole Normale

来源：

POLYMER BULLETIN | 1992年 / 28卷 / 06期

关键词：

D O I：

10.1007/BF00295964

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Methacrylation of triglycidyl triphenyl methane (via methacrylic acid) has been done using three catalysts: dimethyl dodecyl amine (DMDA), tetrabutyl ammonium bromide (TBAB) and chromium (III) diisopropyl salicylate (Cr Dips). The reaction has been followed by epoxy colorimetric titration, CPG and H-1 NMR. This study has shown the superiority of chromium catalysis because of its rapidity and ease of process. Then, these cured products (TACTIX and methacrylated TACTIX) show homogeneous Tg values which are higher than 200-degrees-C.

引用

页码：627 / 632

页数：6

共 21 条

[1] SYNTHESIS AND APPLICATIONS OF PHOTOLINKABLE POLY(DIMETHYLSILOXANES) .2. SYNTHESIS OF POLYSILOXANE WITH URETHANE ACRYLATE GROUPS [J].

ABDELLAH, L ;

BOUTEVIN, B ;

YOUSSEF, B .

EUROPEAN POLYMER JOURNAL, 1991, 27 (08) :821-825

[2]

BARES M, 1979, TENSIDE DETERGENTS, V16, P74

[3]

BAUDUIN G, 1987, MAKROMOL CHEM, V188, P1055

[4] EPOXY-RESINS [J].

BAUER, RS .

ACS SYMPOSIUM SERIES, 1985, 285 :931-961

[5]

BOUTEVIN B, 1989, MAKROMOL CHEM, V190, P2363

[6]

BOUTEVIN B, 1987, MAKROMOL CHEM, V188, P1621

[7]

Boutevin B., 1989, COMPREHENSIVE POLYM, V3, P185

[8]

Chretien G., 1986, MATERIAUX COMPOSITES, P107

[9] FUNCTIONALIZATION OF POLYSILOXANES BY ESTERIFICATION OF PENDANT GLYCIDIC GROUPS - CATALYZED REACTION IN N,N-DIMETHYLFORMAMIDE [J].

COQUERET, X ;

LABLACHECOMBIER, A ;

LOUCHEUX, C .

EUROPEAN POLYMER JOURNAL, 1988, 24 (12) :1137-1143

[10]

EMERSON JB, 1986, RAD CURING POLYM, V64

← 1 2 3 →