THE INFLUENCE OF WATER ON THE CYCLABILITY OF LITHIUM IN 2-METHYLTETRAHYDROFURAN-BASED ELECTROLYTES

被引:7
作者
BARTHEL, J
WUHR, M
SAUERER, W
HEFER, B
机构
[1] Institut für Physikalische und Theoretische Chemie, Universität Regensburg
关键词
D O I
10.1149/1.2056112
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The cycling efficiency of lithium in solutions of LiClO4 and LiI in 2-methyltetrahydrofuran was investigated by galvanostatic experiments and cyclic voltammetry. Traces of water lower the cycling efficiency of LiClO4 solutions, but produce an increase of the cycling efficiency of LiI solutions, diminishing at water content above 500 ppm. Addition of 2-methylfuran shows no effect. An increase of the lithium cycling efficiency of LiClO4/2-methyltetrahydrofuran was observed after addition of small amounts of LiAsF6.
引用
收藏
页码:6 / 11
页数:6
相关论文
共 16 条
[1]  
Abraham K. M., 1983, LITHIUM BATTERIES
[2]   RECENT DEVELOPMENTS IN SECONDARY LITHIUM BATTERY TECHNOLOGY [J].
ABRAHAM, KM .
JOURNAL OF POWER SOURCES, 1985, 14 (1-3) :179-191
[3]   LONG CYCLE-LIFE SECONDARY LITHIUM CELLS UTILIZING TETRAHYDROFURAN [J].
ABRAHAM, KM ;
FOOS, JS ;
GOLDMAN, JL .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1984, 131 (09) :2197-2199
[4]  
Brummer S. B., 1980, Materials for Advanced Batteries. Proceedings of a NATO Symposium on Materials for Advanced Batteries, P123
[5]  
DOMINEY LA, 1989, ELECTROCHEMICAL SOC, P213
[6]  
GOLDMAN JL, 1980, J ELECTROCHEM SOC, V127, P1461
[7]   SOLUBILITY AND SOLVATE FORMATION OF LITHIUM HEXAFLUOROARSENATE IN ACETONITRILE [J].
KILROY, WP .
JOURNAL OF SOLUTION CHEMISTRY, 1977, 6 (07) :487-490
[8]   REACTIONS OF TETRAHYDROFURAN AND LITHIUM HEXAFLUOROARSENATE WITH LITHIUM [J].
KOCH, VR .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1979, 126 (02) :181-187
[9]   STATUS OF THE SECONDARY LITHIUM ELECTRODE [J].
KOCH, VR .
JOURNAL OF POWER SOURCES, 1981, 6 (04) :357-370
[10]   SPECULAR LITHIUM DEPOSITS FROM LITHIUM HEXAFLUOROARSENATE DIETHYL-ETHER ELECTROLYTES [J].
KOCH, VR ;
GOLDMAN, JL ;
MATTOS, CJ ;
MULVANEY, M .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1982, 129 (01) :1-4