The Vibrational Spectra and Structures of Perbromyl and Perchloryl Fluorides

被引:30
作者
Claassen, Howard H. [1 ]
Appelman, Evan H. [1 ]
机构
[1] Argonne Natl Lab, Div Chem, Argonne, IL 60439 USA
关键词
D O I
10.1021/ic50085a038
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Raman and infrared spectra of BrO3F gas and the Raman spectrum of ClO3F gas are reported. The ClO3F results confirm the tetrahedral C-3v symmetry indicated by earlier work, and the BrO3F results support a similar structure for it. The fundamental frequencies of BrO3F are 875.5, 605.0, and 359.8 cm(-1), for species a(1) and 976.5, 382.0, and 286 cm(-1), for species e.
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页码:622 / 624
页数:3
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