ENERGETIC HETEROGENEITY AND MOLECULAR-SIZE EFFECTS IN PHYSICAL ADSORPTION ON SOLID-SURFACES

被引：40

作者：

MARCZEWSKI, AW

DERYLOMARCZEWSKA, A

JARONIEC, M

机构：

[1] Marie Curie-Sklodowska Univ, Inst of, Chemistry, Lublin, Pol, Marie Curie-Sklodowska Univ, Inst of Chemistry, Lublin, Pol

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 1986年 / 109卷 / 02期

关键词：

MOLECULES;

D O I：

10.1016/0021-9797(86)90309-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A simple model of adsorption processes involving simultaneously adsorbent heterogeneity and adsorbate molecule size is presented. The considerations concern adsorption from the gas as well as liquid phases on solids characterized by different surface topographies. Relationships between energy distribution functions and molecular size are derived and the form of the isotherm equation is discussed. The theoretical considerations are illustrated by some model calculations.

引用

页码：310 / 324

页数：15

共 16 条

[1] ADSORPTIVE MECHANISM ON ACTIVATED CARBON IN THE LIQUID-PHASE .3. THE RELATIONSHIP BETWEEN THE PHYSICAL CONSTANTS OF ORGANIC-COMPOUNDS AND THEIR ADSORBABILITIES ON ACTIVATED CARBON FROM AN AQUEOUS-SOLUTION [J].

ABE, I ;

HAYASHI, K ;

KITAGAWA, M ;

URAHATA, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1980, 53 (05) :1199-1205

[2] CHARACTERIZATION OF SOLID-LIQUID ADSORPTION SYSTEMS BY USING GAUSSIAN ENERGY-DISTRIBUTION [J].

DABROWSKI, A ;

JARONIEC, M .

MATERIALS CHEMISTRY AND PHYSICS, 1985, 12 (04) :339-365

[3]

ELOVIN C, 1962, IZV AKAD NAUK SSSR K, V62, P531

[4] THERMODYNAMICS OF ADSORPTION FROM SOLUTION .2. IMPERFECT SYSTEMS [J].

EVERETT, DH .

TRANSACTIONS OF THE FARADAY SOCIETY, 1965, 61 (515P) :2478-&

[5]

EVERETT DH, 1973, SPECIALIST PERIODICA, V1

[6] ADSORPTION OF 1-OLEFIN/NORMAL-PARAFFIN LIQUID-MIXTURES ON NAX AND NAY ZEOLITES [J].

JARONIEC, M ;

DABROWSKI, A ;

NOWAKOWSKI, G ;

HERDEN, H ;

EINICKE, WD ;

SCHOLLNER, R .

JOURNAL OF INCLUSION PHENOMENA, 1985, 3 (01) :85-93

[7] AN EQUATION FOR MULTI-SOLUTE ADSORPTION FROM DILUTE AQUEOUS-SOLUTIONS INVOLVING ENERGETIC HETEROGENEITY OF THE SOLID AND DIFFERENCES IN MOLECULAR SIZES OF THE SOLUTES [J].

JARONIEC, M ;

DERYLO, A ;

MARCZEWSKI, AW .

CHEMICAL ENGINEERING SCIENCE, 1983, 38 (02) :307-311

[8] A SIMPLE-MODEL FOR THE ADSORPTION OF MIXTURES ON SOLIDS INVOLVING ENERGETIC HETEROGENEITY OF THE SURFACE AND DIFFERENCES IN MOLECULAR SIZES OF THE COMPONENTS [J].

JARONIEC, M .

THIN SOLID FILMS, 1981, 81 (01) :L97-L99

[9] COMPETITIVE ADSORPTION OF BINARY GAS-MIXTURES ON ENERGETICALLY HETEROGENEOUS SOLIDS [J].

JARONIEC, M ;

MARCZEWSKI, AW .

THIN SOLID FILMS, 1982, 92 (04) :385-391

[10]

PATRYKIEJEW A, 1983, CHEM SCRIPTA, V22, P136

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