EFFICIENT SYNTHESIS OF (ETA-5-CYCLOPENTADIENYL)(ETA-3-ALLYL)MO(CO)2 COMPLEXES FROM ALLYLIC DIPHENYLPHOSPHINATES

被引：16

作者：

MCCALLUM, JS ^{[1
]}

STERBENZ, JT ^{[1
]}

LIEBESKIND, LS ^{[1
]}

机构：

[1] EMORY UNIV, DEPT CHEM, ATLANTA, GA 30322 USA

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 03期

关键词：

D O I：

10.1021/om00027a048

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(eta5-Cyclopentadienyl)(eta3-allyl)Mo(CO)2 complexes are readily prepared by the reaction of molybdenum hexacarbonyl or tris(acetonitrile)molybdenum tricarbonyl with allylic diphenylphosphinates followed by treatment with cyclopentadienyllithium. The yields, accessibility of precursors, and operational simplicity of this method compare favorably with existing methods based upon allylic halides.

引用

页码：927 / 932

页数：6

共 80 条

[1] STEREOSPECIFICITY IN REACTIONS OF ACTIVATED ETA-3-ALLYL COMPLEXES OF MOLYBDENUM [J].