INTERPRETATION OF THE VIBRATIONAL-SPECTRA OF PLANARIZED POLY-P-PHENYLENE

被引：25

作者：

CUFF, L ^{[1
]}

KERTESZ, M ^{[1
]}

SCHERF, U ^{[1
]}

MULLEN, K ^{[1
]}

机构：

[1] MAX PLANCK INST POLYMER RES, W-6500 MAINZ, GERMANY

来源：

SYNTHETIC METALS | 1995年 / 69卷 / 1-3期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0379-6779(94)02613-4

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We present an interpretation of the Raman and IR spectra of planarized poly(p-phenylene). The newly synthesized PPP, planarized with methylene bridging groups, is predicted to have a much higher inter-ring stretching frequency although the inter-ring bond length (1.475 Angstrom) is only slightly shorter than that of pristine PPP. This is supported by the Raman spectrum of a substituted planarized PPP. The IR spectrum of planarized PPP is predicted to have strong peaks in the 1350-1450 cm(-1) region. The C-H out-of-plane bending mode was found to be 840 cm(-1) which is consistent with that of a 1,2,4,5, tetrasubstituted phenyl ring.

引用

页码：683 / 684

页数：2

共 12 条

[1] AB-INITIO OLIGOMER APPROACH TO VIBRATIONAL-SPECTRA OF POLYMERS - COMPARISON OF HELICAL AND PLANAR POLY(P-PHENYLENE) [J].