BRIDGED BIS(DICARBADODECABORANE)COBALT(III)

被引：10

作者：

CISAROVA, I ^{[1
]}

MALY, K ^{[1
]}

HUMMEL, L ^{[1
]}

机构：

[1] CZECHOSLOVAK ACAD SCI,INST PHYS,CS-18040 PRAGUE 8,CZECH REPUBLIC

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270193007127

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The molecule of 8,8'-mu-(methoxycarbonylmethyl-amino)-3,3'-commo-bis[1,2-dicarba-3-cobalta-closo-dodecaborane(II)], [Co(C7H26B18NO2)], comprises two dicarbaborane ligands coordinated to the Co atom to form a 'sandwich' compound linked by pentagonal faces. The ligands are also linked by a monoatomic nitrogen bridge to which a methoxycarbonylmethyl group is bound, B-N bond lengths being 1.577 (4) and 1.563 (4) angstrom.

引用

页码：198 / 200

页数：3

共 7 条

[1] CRYSTAL AND MOLECULAR-STRUCTURE OF (C2H5)3NH+[CO(1,2-C2B9H11)2]- [J].

BORODINSKY, L ;

SINN, E ;

GRIMES, RN .

INORGANIC CHEMISTRY, 1982, 21 (04) :1686-1689

[2] STRUCTURE OF 8,8'-MU-(METHOXYCARBONYLMETHYLTHIO)-3,3'-COMMO-BIS[1,2-DICARBA-3-COBALTA-CLOSO-DODECABORANE(11)] [J].

CISAROVA, I ;

PETRICEK, V .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1986, 42 :663-665

[3] FASTER DATA-COLLECTION WITHOUT LOSS OF PRECISION - AN EXTENSION OF THE LEARNT PROFILE METHOD [J].

CLEGG, W .

ACTA CRYSTALLOGRAPHICA SECTION A, 1981, 37 (JAN) :22-28

[4] SYNTHESIS AND CHARACTERISTICS OF SULFUR INTERLIGAND BRIDGE-DERIVATIVES AND OF SOME S-SUBSTITUTED COMPOUNDS IN THE (C2B9H11)2CO-SERIES - CONFORMATIONS OF (C2B9H11)2MX-METALLOCARBORANES [J].

JANOUSEK, Z ;

PLESEK, J ;

HERMANEK, S ;

BASE, K ;

TODD, LJ ;

WRIGHT, WF .

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1981, 46 (11) :2818-2833

[5]

PETRICEK V, 1981, SYSTEM COMPUTER PROG

[6] ZWITTERIONIC COMPOUNDS OF 8,8'-X(C2B9H10)2CO SERIES WITH MONOATOMIC O, S, SE, TE, N BRIDGES BETWEEN CARBORANE LIGANDS [J].

PLESEK, J ;

HERMANEK, S ;

BASE, K ;

TODD, LJ ;

WRIGHT, WF .

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1976, 41 (12) :3509-3515

[7] THE GEOMETRY OF THE N-H ... O=C HYDROGEN-BOND .3. HYDROGEN-BOND DISTANCES AND ANGLES [J].

TAYLOR, R ;

KENNARD, O ;

VERSICHEL, W .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1984, 40 (JUN) :280-288

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