EXPERIMENTAL-EVIDENCE FOR AN ISOMERIC TRANSITION OF SIZE-SELECTED METHANOL HEXAMERS

被引：40

作者：

BUCK, U

ETTISCHER, I

机构：

[1] Max-Planck-Institut für Strömungsforschung

来源：

JOURNAL OF CHEMICAL PHYSICS | 1994年 / 100卷 / 09期

关键词：

D O I：

10.1063/1.467014

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We have measured the predicted isomeric transition between the two energetically lowest lying isomers of S-6 and C-2 symmetry of (CH3OH)(6). The clusters are size selected by momentum transfer in collisions with He, and identified by their infrared spectra. The transition occurs at a nozzle temperature of 368 K corresponding to a cluster temperature of 23 K.

引用

页码：6974 / 6976

页数：3

共 27 条

[1] [Anonymous], 1979, ADV CHEM PHYS, DOI DOI 10.1002/9780470142592.CH2
[2] BERRY RS, 1990, P INT SCH PHYS, V107, P23
[3] BERRY RS, 1988, ADV CHEM PHYS, V70, P74
[4] BILLING GD, 1986, CHEM PHYS, V104, P19, DOI 10.1016/0301-0104(86)80149-5
[5] BLEIBER A, COMMUNICATION
[6] ELECTRON-BOMBARDMENT FRAGMENTATION OF AR VAN DER WAALS CLUSTERS BY SCATTERING ANALYSIS
BUCK, U
MEYER, H
[J]. JOURNAL OF CHEMICAL PHYSICS, 1986, 84 (09) : 4854 - 4861
[7] INFRARED PHOTODISSOCIATION OF SIZE-SELECTED METHANOL CLUSTERS
BUCK, U
GU, XJ
LAUENSTEIN, C
RUDOLPH, A
[J]. JOURNAL OF CHEMICAL PHYSICS, 1990, 92 (10) : 6017 - 6029
[8] A PERTURBATION APPROACH TO PREDICT INFRARED-SPECTRA OF SMALL MOLECULAR CLUSTERS APPLIED TO METHANOL
BUCK, U
SCHMIDT, B
[J]. JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (12) : 9410 - 9424
[9] PROPERTIES OF NEUTRAL CLUSTERS FROM SCATTERING EXPERIMENTS
BUCK, U
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (05) : 1023 - 1031
[10] IR DOUBLE-RESONANCE EXPERIMENTS WITH SIZE-SELECTED CLUSTERS FOR IDENTIFICATION OF ISOMERS
BUCK, U
HOBEIN, M
[J]. ZEITSCHRIFT FUR PHYSIK D-ATOMS MOLECULES AND CLUSTERS, 1993, 28 (04): : 331 - 337

← 1 2 3 →