MU-(O,O'-DIETHYL DITHIOPHOSPHATO-2-KAPPA-S-3-KAPPA-S')-OXO-1-KAPPA-O-TRI-MU(3)-SULFIDO-1-2-3-KAPPA(3)S-1-2-4-KAPPA(3)S-1-3-4-KAPPA(3)S-TRIS(TRIPHENYLPHOSPHINE)-2-KAPPA-P-3-KAPPA-P-4-KAPPA-P-TRICOPPERTUNGSTEN

被引:6
作者
DU, SW
WU, XT
机构
关键词
D O I
10.1107/S0108270193009023
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The structure of the title comopound, [WCu3(O)S3(C4H10O2PS2)(C18H15P)3], contains an incomplete cubane-like cluster core, [WCu3S3{S2P(OCH2CH3)2}]2+, in,which the two S atoms of the diethyl dithiophosphato ligand coordinate to two Cu atoms with bond lengths of 2.472 (3) angstrom [Cu(1)-S(4)] and 2.337 (3) angstrom [Cu(3)-S(5)].
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页码:500 / 502
页数:3
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