CATION-EXCHANGE PROPERTIES OF HYDROTHERMALLY TREATED COAL FLY-ASH

被引：168

作者：

SINGER, A

BERKGAUT, V

机构：

[1] Seagram Centre for Soil and Water Science, Hebrew University of Jerusalem, Rehovot 76100

来源：

ENVIRONMENTAL SCIENCE & TECHNOLOGY | 1995年 / 29卷 / 07期

关键词：

D O I：

10.1021/es00007a009

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Two samples of fly ash were treated for 2-48 h in 3.5 M NaOH at 100 degrees C. Powder XRD patterns of resulting products were obtained, and their CEC was determined. Zeolite P and/or hydroxysodalite formed during the treatment from the glassy part of fly ash, while quartz gradually dissolved and mullite remained stable. Approximately 50% of fly ash could be converted to zeolites with the CEC of resulting products reaching 2.5-3 mequiv/g. Concentrations of extractable B, Mo, and Se in fly ash considerably decreased upon treatment. Adsorption isotherms of lead on treated fly ash suggested that at low initial lead concentrations and at pH lower than 6 precipitation of lead compounds is not likely. A desorption experiment indicated ii incomplete reversibility at higher concentrations, suggesting that part of the adsorption may not have been cation exchange related. Treated fly ash displayed high selectivity for Pb2+ > Sr2+ > CU2+ > Cd2+ > Zn2+ > Cs+ in competition with Na+, especially at low concentrations of these cations, and was effective in removing Pb and Zn from industrial wastewaters. It was not selective for Ni2+ and UO22+. In a column test, 160 bed vols of NH4+-contaminated fish-pond water was filtered through treated fly ash until NH4+ breakthrough occurred.

引用

页码：1748 / 1753

页数：6

共 22 条

[1] McCarthy G.J., Solem J.K., Adv. X-ray Anal., 34, pp. 387-394, (1991)
[2] Holler H., Wirsching U., Fortschr. Mineral., 63, (1985)
[3] Henmi T., Clay Sei., 6, pp. 277-282, (1987)
[4] Mondragon F., Rincon F., Sierra L., Escobar J., Ramirez J., Fernandez J., Fuel, 69, (1990)
[5] Shigemoto N., Shirakami K., Hirano S., Hayashi H., Nippon Kagaku Kaishi, 1992, (1992)
[6] Catalfamo P., Corigliano F., Primerano P., Di Pasquale S., J. Chem. Soc. Faraday Trans., 89, pp. 171-175, (1993)
[7] Jackson M.L., Soil Chemical Analysis-Advanced Course, (1974)
[8] Polemio M., Rhoades J.D., Soil Sei. Soc. Am. J., 41, pp. 524-528, (1977)
[9] Basta N.T., Tabatabai M.A., Soil Sei., 153, pp. 195-204, (1992)
[10] Keeney D.R., Nelson D.W., Methods of Soil Analysis, pp. 643-698, (1982)

← 1 2 3 →