THE STUDY OF ELECTRONIC-STRUCTURE OF MOLYBDENUM AND TUNGSTEN TRISULFIDES AND THEIR LITHIUM INTERCALATES BY X-RAY ELECTRON AND X-RAY-EMISSION AND ABSORPTION-SPECTROSCOPY

被引：22

作者：

KHUDOROZHKO, GF

ASANOV, IP

MAZALOV, LN

KRAVTSOVA, EA

PARYGINA, GK

FEDOROV, VE

MIRONOV, JV

机构：

[1] Institute of Inorganic Chemistry, RAS Siberian brahch, Novosibirsk, 630090

来源：

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 1994年 / 68卷

关键词：

D O I：

10.1016/0368-2048(94)02200-3

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The distribution of electron density in cathode materials MoS3 and WS3 during their lithiation has been studied by X-ray electron and X-ray emission and absorption spectroscopies. It is demonstrated that the lithium electrons localize both on metal and on sulfur atoms but mainly on disulfide atoms. Presence of a complementary bond of donor-acceptor nature has been proposed. On a basis of this assumption and X-ray emission spectra. the electron structure of MoS3 has been suggested.

引用

页码：199 / 209

页数：11

共 25 条

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