ELECTRONIC SPECTRAL EFFECTS ON CHIRAL SURFACE 2ND-HARMONIC GENERATION

被引：62

作者：

BYERS, JD

HICKS, JM

机构：

[1] Department of Chemistry, Georgetown University, Washington

来源：

CHEMICAL PHYSICS LETTERS | 1994年 / 231卷 / 2-3期

关键词：

D O I：

10.1016/0009-2614(94)01244-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A molecular level interpretation of the chiroptical effects observed in surface second harmonic generation from a chiral surface is presented. A Pariser, Parr and Pople molecular orbital treatment is used to calculate the hyperpolarizability of R-2,2'-dihydroxy-1,1'-binaphthyl (R-BN). The chiroptical spectra from monolayers of R-BN are calculated using various assumed molecular orientational distributions, and the model spectra compare favorably with experimental data.

引用

页码：216 / 224

页数：9

共 23 条

[1] Butcher P. N., 1990, ELEMENTS NONLINEAR O
[2] A 2ND-HARMONIC GENERATION ANALOG OF OPTICAL-ROTATORY DISPERSION FOR THE STUDY OF CHIRAL MONOLAYERS
BYERS, JD
YEE, HI
HICKS, JM
[J]. JOURNAL OF CHEMICAL PHYSICS, 1994, 101 (07) : 6233 - 6241
[3] 2ND-HARMONIC GENERATION CIRCULAR-DICHROISM SPECTROSCOPY FROM CHIRAL MONOLAYERS
BYERS, JD
YEE, HI
PETRALLIMALLOW, T
HICKS, JM
[J]. PHYSICAL REVIEW B, 1994, 49 (20): : 14643 - 14647
[4] COTTON FA, 1971, CHEM APPLICATIONS GR
[5] DELBENE J, 1968, J CHEM PHYS, V48, P1807
[6] THE CONTRIBUTION OF PI-ELECTRONS TO 2ND HARMONIC-GENERATION IN ORGANIC-MOLECULES
DIRK, CW
TWIEG, RJ
WAGNIERE, G
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (18) : 5387 - 5395
[7] OPTICAL ROTATORY POWER OF 2,2'-DIHYDROXY-1,1'-BINAPHTHYL AND RELATED COMPOUNDS
HANAZAKI, I
AKIMOTO, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (12) : 4102 - &
[8] Heinz T., 1982, THESIS U CALIFORNIA
[9] DETERMINATION OF MOLECULAR-ORIENTATION OF MONOLAYER ADSORBATES BY OPTICAL 2ND-HARMONIC GENERATION
HEINZ, TF
TOM, HWK
SHEN, YR
[J]. PHYSICAL REVIEW A, 1983, 28 (03): : 1883 - 1885
[10] HICKS JM, IN PRESS FARADAY DIS, V99

← 1 2 3 →